منابع مشابه
Infrared absorption spectra of vinyl radicals isolated in solid Ne.
Irradiation of samples of solid Ne near 3.0 K containing ethene (C(2)H(4)) with vacuum ultraviolet radiation at 120 nm from synchrotron yielded new spectral lines at 3141.0, 2953.6, 2911.5, 1357.4, 677.1, 895.3, and 857.0 cm(-1). These features are assigned to alpha-CH stretching (nu(1)), CH(2) antisymmetric stretching (nu(2)), CH(2) symmetric stretching (nu(3)), CH(2)-bending (nu(5)), HCCH cis...
متن کاملSoft X-ray absorption spectra of aqueous salt solutions with highly charged cations in liquid microjets
0009-2614/$ see front matter 2010 Published by doi:10.1016/j.cplett.2010.05.037 * Corresponding author. Address: Department of C fornia, D31 Hildebrand, Berkeley, CA 94720-1460, US E-mail address: [email protected] (R.J. Saykal X-ray absorption spectra of 1 M aqueous solutions of indium(III) chloride, yttrium(III) bromide, lanthanum(III) chloride, tin(IV) chloride and chromium(III) chloride...
متن کاملEffects of Nanoclay on Cellular Morphology and Water Absorption Capacity of Poly(vinyl alcohol) Foam
The present work was aimed to examine the effects of incorporation of each of two different types of nanoclay, i.e. Cloisite Na+ and Cloisite 30B, into PVA foam on cellular morphology and water absorption capacity. Foam samples containing 0.0-10.0 wt% of each of the two types of nanoclay alone were prepared using mechanical foaming. Accordingly, PVA/organoclay/water suspensions were prepare...
متن کاملRemote C-H insertion of vinyl cations leading to cyclopentenones.
We report a Lewis acid catalyzed reaction sequence involving a 1,2-shift and subsequent C-H insertion that gives monocyclic and fused bicyclic cyclopentenone products. This reaction sequence, which is initiated by treating β-hydroxy-α-diazo ketones with a Lewis acid, proceeds through vinyl cation intermediates that insert at non-activated gamma C-H bonds. This reaction represents an alternative...
متن کاملAbsorption Spectra of Phytochrome Intermediates
Native phytochrome (124kdalton) was isolated from etiolated seedlings o f Avena sativa L. cv. Pirol (Baywa, Munich). From low temperature spectra (0 °C to — 165°C ) o f phytochrom e samples irradiated either with red or far-red light, spectra o f intermediates were calculated. Both absorption bands o f the phytochrome chromophore were reported. On the pathway P r i V r , native phytochrome does...
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ژورنال
عنوان ژورنال: Chemistry Letters
سال: 1983
ISSN: 0366-7022,1348-0715
DOI: 10.1246/cl.1983.1117